21:00 – tirsdag 1 oktober, 2019
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| Røde Stjerne | 3-1 | Olympiakos |
Fulltid
 | ||
| 90' |  | Vassilis Torosidis |
| Marko Marin | | 90' |
| 3-1 Richmond Boakye |  | 90' |
| 89' |  | Youssef El-Arabi Mohamed Camara |
| 2-1 Nemanja Milunović | | 87' |
| Njegoš Petrović | | 83' |
| Richmond Boakye | | 80' |
| 79' | | Omar Elabdellaoui Giorgos Masouras |
Njegoš Petrović Cañas | | 73' |
| 1-1 Miloš Vulić | | 62' |
Richmond Boakye Rajiv van La Parra | | 61' |
| 61' | | Daniel Podence Maximiliano Lovera |
| 58' |  | Yassine Benzia |
Miloš Vulić Dušan Jovančić | | 55' |
| Pause 0-1 | ||
| 42' | | Yassine Benzia |
| 37' | | 0-1 Rúben Semedo |
| Rajiv van La Parra | | 36' |
| Milan Rodić | | 26' |
| ||